Identification of topmost atom on InP (001) surface by coaxial impact collision ion scattering spectroscopy
Identifieur interne : 000049 ( Main/Exploration ); précédent : 000048; suivant : 000050Identification of topmost atom on InP (001) surface by coaxial impact collision ion scattering spectroscopy
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Abstract
The topmost atom of InP (001) surfaces, which were annealed at temperatures between 300 and 550°C or sputtered with 1 keV Ar+ at 300°C in ultra high vacuum, has been directly identified by means of coaxial impact collision ion scattering spectroscopy (CAICISS). Time-of-flight spectra of the annealed InP (001) surface exhibited both In and P peaks in both$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and in [100] azimuth, which revealed that the topmost layer of annealed InP (001) was comprised of In-terminated and P-terminated surfaces. On the other hand, time-of-flight spectrum of the InP (001) sputtered at 300°C revealed only an In peak in$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and revealed both In and P peaks in [100] azimuth. This result indicates that the topmost layer on the Ar+-sputtered InP (001) surface was completely terminated by In atoms. Furthermore, we indicate that surface damage induced by this sputtering treatment is little. The azimuthal depen-dence of CAICISS intensity scattered from In and P showed twofold symmetry with respect to [100] direction, which originated from the zinc-blende structure.
DOI: 10.1007/BF02666521
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<author><name>T. Nishihara</name>
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<author><name>M. Shinohara</name>
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<author><name>O. Ishiyama</name>
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<author><name>F. Ohtani</name>
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<author><name>M. Yoshimoto</name>
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<author><name>T. Maeda</name>
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<author><name>H. Koinuma</name>
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<front><div type="abstract" xml:lang="eng">The topmost atom of InP (001) surfaces, which were annealed at temperatures between 300 and 550°C or sputtered with 1 keV Ar+ at 300°C in ultra high vacuum, has been directly identified by means of coaxial impact collision ion scattering spectroscopy (CAICISS). Time-of-flight spectra of the annealed InP (001) surface exhibited both In and P peaks in both$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and in [100] azimuth, which revealed that the topmost layer of annealed InP (001) was comprised of In-terminated and P-terminated surfaces. On the other hand, time-of-flight spectrum of the InP (001) sputtered at 300°C revealed only an In peak in$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and revealed both In and P peaks in [100] azimuth. This result indicates that the topmost layer on the Ar+-sputtered InP (001) surface was completely terminated by In atoms. Furthermore, we indicate that surface damage induced by this sputtering treatment is little. The azimuthal depen-dence of CAICISS intensity scattered from In and P showed twofold symmetry with respect to [100] direction, which originated from the zinc-blende structure.</div>
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<abstract lang="eng">The topmost atom of InP (001) surfaces, which were annealed at temperatures between 300 and 550°C or sputtered with 1 keV Ar+ at 300°C in ultra high vacuum, has been directly identified by means of coaxial impact collision ion scattering spectroscopy (CAICISS). Time-of-flight spectra of the annealed InP (001) surface exhibited both In and P peaks in both$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and in [100] azimuth, which revealed that the topmost layer of annealed InP (001) was comprised of In-terminated and P-terminated surfaces. On the other hand, time-of-flight spectrum of the InP (001) sputtered at 300°C revealed only an In peak in$$[\overline {\text{1}} {\text{ }}10]$$ azimuth and revealed both In and P peaks in [100] azimuth. This result indicates that the topmost layer on the Ar+-sputtered InP (001) surface was completely terminated by In atoms. Furthermore, we indicate that surface damage induced by this sputtering treatment is little. The azimuthal depen-dence of CAICISS intensity scattered from In and P showed twofold symmetry with respect to [100] direction, which originated from the zinc-blende structure.</abstract>
<subject lang="eng"><genre>Key words</genre>
<topic>Ar sputtering</topic>
<topic>coaxial impact collision ion scattering spectroscopy (CAICISS)</topic>
<topic>indium phosphide</topic>
<topic>ion scattering spectroscopy</topic>
<topic>surface analysis</topic>
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<titleInfo><title>Journal of Electronic Materials</title>
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<originInfo><dateIssued encoding="w3cdtf">1996-05-01</dateIssued>
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<subject usage="primary"><topic>Chemistry</topic>
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<topic>Characterization and Evaluation of Materials</topic>
<topic>Solid State Physics and Spectroscopy</topic>
<topic>Electronics and Microelectronics, Instrumentation</topic>
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<part><extent unit="pages"><start>667</start>
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